Batteries used in hazardous areas must be intrinsically safe. IBM 08K8192 Battery, IBM 92P1101 Battery, IBM 92P1089 Battery, IBM 92P1087 Battery, Hazardous areas include oil refineries, mines, grain elevators and fuel handling at airports. These areas are typically serviced with two-way radios and computing devices. Intrinsically safe batteries prevent excessive heat buildup and the danger of an electric spark on equipment failure. Because of tight approval standards, intrinsically safe batteries carry twice to three-times the price tag of regular packs.

Another battery that contains high-level protection is lithium-ion. This is done to assure safety under all circumstances while in the hands of the public. Typically, a Field Effect Transistor (FET) opens if the charge voltage of any cell reaches 4.30V. A separate fuse opens if the cell temperature approaches 90°C (194°F). In addition, a disconnect switch in each cell permanently interrupts the charge current if a safe pressure threshold of about 10 Bar (150 psi) is exceeded. To prevent the battery from over-discharging, the control circuit cuts off the current path at about 2.50V/cell. Prolonged storage at voltages of 1.5V/cell and lower damages the lithium-ion, causing safety problems if attempted to recharge.

Figure 1: A common safety circuit for cellular phone applications.
Because of improved thermal stability of manganese-based lithium-ion, IBM 92P1101 Battery manufacturers relax the need for an external safety circuit on packs with two cells in series.

Each parallel string of cells in a lithium-ion pack needs independent voltage monitoring. IBM 08K8192 Battery, IBM 92P1101 Battery, IBM 92P1089 Battery, IBM 92P1087 Battery,In addition, each cell in series must be monitored for voltage. The more cells that are connected in series, the more complex the protection circuit becomes. Four cells in series is the practical limit for commercial applications.

The internal protection circuit must be designed to add as little resistance as possible to the current path. The circuit of a cell phone battery often consists of two FET switches connected in series. One FET is responsible for high, the other for low voltage cut-off. The combined resistance of the FETs in the ON position is 50-100milli Ohms (mW). This virtually doubles the internal resistance of a battery pack.

A major concern arises if static electricity or a faulty charger destroys the battery's protection circuit. This may result in permanently fusing the solid-state switches in an ON position without the user's knowledge. A battery with a faulty protection circuit may function normally but will not provide protection. If charged over a voltage limit (4.20V/cell should not be exceeded) with a defective charger, venting with flame could occur. Such a situation must be avoided at all cost. Shorting such a battery could also be hazardous.

Low-cost cell phone batteries have infiltrated the world market since the beginning of 2003,IBM 92P1089 Battery . These counterfeit batteries often do not have an approved protection circuit and can vent with flame if the charger malfunctions. Cell phone manufacturers strongly advise customers to replace the battery with an approved brand. Failing to do so may void the warranty. It is also highly recommended to only use approved chargers. (See photos of an exploded cell phone with a clone battery that was on charge.)

Figure 2: Damaged cell phone.
A cell phone with a no-brand battery vented with flame while charging in the back of a car.

When advising on the choice of batteries and chargers, cell phone manufacturers act out of genuine concern for safety rather than using scare tactics to persuade customers to buy their own accessories. They do not object third parties as long as the products are well built and safe. The buyer can often not distinguish between an original and a counterfeit battery because the label may appear bona fide.

Small lithium-ion packs with spinel (manganese) chemistry containing one or two cells may only include a fuse as protection. IBM 08K8192 Battery, IBM 92P1101 Battery, IBM 92P1089 Battery, IBM 92P1087 Battery,Spinel is more tolerant to abuse than cobalt and the cells are deemed safe if below a certain size.

Although less expensive, the absence of a protection circuit introduces a new problem. Cell phone users have access to low-cost chargers that may rely on the battery's protection circuit to terminate charge. Without the protection circuit, the cell voltage rises too high and damages the battery. Excess heat,IBM 92P1087 Battery even bulging can result. Discontinue using the battery and charger if a lithium-ion battery gets hot.

Figure 3: Budging of a lithium-ion cell.
Prismatic Lithium-ion cells are subject to budging, causing stress on the battery compartment of portable devices.

To maintain safe operation, manufacturers do not sell the lithium-ion cells by themselves but make them available in a battery pack, complete with protection circuit. The circuit is often subject to exact scrutiny before the manufacturers release cells to the pack assemblers. Although there are a few reported incidents of venting with flame, the lithium-ion battery is safe.